NAVIGATION
QUICK INQUIRY
Chagnes, Alexandre, et al. Hydrometallurgy, 2010, 104(1), 20-24.
Vanadium(V) extraction from acidic sulfate media was achieved using protonated trioctylamine in n-dodecane modified with 5% (wt) 1-tridecanol.
Experimental procedures and results
· The work examined the speciation of vanadium (V) extracted from acidic sulfate media using protonated trioctylamine in n-dodecane modified with 5% (wt) 1-tridecanol, through Fourier transform infrared spectroscopy (FTIR) and 51V nuclear resonance spectroscopy (51V NMR).
· In solutions containing 0.02-0.1 mol/kg vanadium (V) in 0.2-1 mol/kg HClO4, the presence of VO2+ was detected by 51V NMR. In similar acidic conditions but in H2SO4 media, speciation calculations suggest the coexistence of VO2+ and VO2SO4- in the aqueous phase, despite the observation of a unique 51V NMR signal at -545 ppm similar to the HClO4 solution, along with a vibration band at 998 cm-1.
· The FTIR spectra of 0.2 mol/kg protonated trioctylamine in n-dodecane modified with 5% (wt) 1-tridecanol, loaded with varying concentrations of vanadium (V) extracted from 1 mol/kg H2SO4, indicate the presence of vanadium (V) in organic phases as likely polyvanadates, such as decavanadates. The 51V NMR did not confirm or rule out this finding, as the micellar structure of the organic phases affects the chemical shift of the extracted species.
What is the molecular formula of 1-Tridecanol?
The molecular formula of 1-Tridecanol is C13H28O.
What is the molecular weight of 1-Tridecanol?
The molecular weight of 1-Tridecanol is 200.36 g/mol.
What is the IUPAC name of 1-Tridecanol?
The IUPAC name of 1-Tridecanol is tridecan-1-ol.
What is the InChI of 1-Tridecanol?
The InChI of 1-Tridecanol is InChI=1S/C13H28O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h14H,2-13H2,1H3.
What is the InChIKey of 1-Tridecanol?
The InChIKey of 1-Tridecanol is XFRVVPUIAFSTFO-UHFFFAOYSA-N.
What is the canonical SMILES of 1-Tridecanol?
The canonical SMILES of 1-Tridecanol is CCCCCCCCCCCCCO.
What is the CAS number of 1-Tridecanol?
The CAS number of 1-Tridecanol is 112-70-9.
What is the ChEBI ID of 1-Tridecanol?
There is no ChEBI ID provided for 1-Tridecanol in the reference.
What is the UNII of 1-Tridecanol?
The UNII of 1-Tridecanol is 8I9428H868.
What is the Wikipedia page for 1-Tridecanol?
The Wikipedia page for 1-Tridecanol is "1-Tridecanol".
